Gideon at Clos Saron
Gideon Beinstock
originally posted by SFJoe:
Thanks, Gideon, very interesting.
Sulfite also binds various flavor components.
It is also possible that certain flavors of light oxidation that might have been bound by sulfites (aldehydes, some alpha-beta unsaturated carbonyl compounds, etc.) that may be part of "bottle shock" may also go away over time as they slowly combine with active phenolics and so on. I'm making that up, and Professor Lipton can correct me, but it seems fairly reasonable.
I have certainly seen early "oxydation" vanish in time. Often in our whites and rose, a couple of times with Pinot. I also have seen bret aromas decrese in time - not vanish, but somehow get re-integrated in the wine to some degree. And early signs of high VA sometime seem to get re-intergrated.
I am certainly not claiming that all "problems" and "spoilage" vanish and go away with further aging, but in my experience, if the wine is well constituted & balanced and has a good aging ability, many early pimples will indeed vanish in time.
To acknowledge Keith's earlier comment, I did observe a higher rate of problems surface in some of our 375ml bottlings.